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Access in nanoporous materials by Thomas J. Pinnavaia, M. F. Thorpe

By Thomas J. Pinnavaia, M. F. Thorpe

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E. Gier, P. Sieger, A. Firouzi, B. F. Chmelka, F. Schuth, and G. D. Stucky, "Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposites Biphase Arrays," Chem. , 6, 1176-1191 (1994). 10. P. T. Tanev and T. J. Pinnavaia, "A Neutral Templating Route to Mesoporous Molecular Sieves," Science, 267, 865-867 (1995). 11. M. J. Rosen, Chapter 4: Solubilization by solutions of surfactants: Micellar catalysis, in: "Surfactants and Interfacial Phenomena," Wiley, New York (1989). 37 This page intentionally left blank.

J. C. S. S. C. J. E. T. D. T-W. H. W. B. McCullen. B. L. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystal templates, J. Am. Chem. Soc. 114: 10834 (1992); 21. V. Luzzati, X-ray diffraction studies of lipid-water systems, in : “Biological Membranes,” D. , Academic, New York (1968) pp. 71-123. 22. S. Inagaki, Y. Fukushima, and K. Kuroda, Synthesis of Highly ordered mesoporous materials from a layered polysilicate, J. Chem. Soc. Chem. Commun. 8: 680 (1993). 23. A.

Although this chemistry seems quite simple, it is its complexity that gives rise to the richly structured carbons that display molecular sieving properties. Most polymers will degrade upon heating above their decomposition temperatures, but relatively few will meet the necessary criterion of generating a high yield of carbon. A few 40 polymers do meet this criterion including natural cellulosics and sugars, and synthetic Saran, polyacrylonitrile (PAN), and polyfurfuryl alcohol (PFA) to name a few (Table 1).

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