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Handbook of Heterogenous Kinetics by Michel Soustelle(auth.)

By Michel Soustelle(auth.)

This booklet provides all of the theoretical and sensible basements of heterogeneous kinetics and reactivity of solids. It applies the hot techniques of reactivity and spatial functionality, brought by way of the writer, for either nucleation and progress processes, with a unified presentation of the reactivity of bulk and powder solids, together with gas-solid reactions, thermal decompositions, solid-solid reactions, reactions of good strategies, and coalescence of strong grains. It additionally contains many workouts and issues of suggestions integrated, permitting readers to appreciate and use all of the recommendations and techniques mentioned therein.Content:
Chapter 1 Definitions and Experimental strategy (pages 1–28): Michel Soustelle
Chapter 2 the genuine stable (pages 29–58): Michel Soustelle
Chapter three Thermodynamics of Heterogenous structures (pages 59–104): Michel Soustelle
Chapter four basic Steps in Heterogenous Reactions (pages 105–130): Michel Soustelle
Chapter five Chemical Diffusion (pages 131–168): Michel Soustelle
Chapter 6 Chemical Adsorption (pages 169–194): Michel Soustelle
Chapter 7 Mechanisms and Kinetics of a strategy (pages 195–256): Michel Soustelle
Chapter eight Nucleation of a brand new good part (pages 257–308): Michel Soustelle
Chapter nine development of a superb part (pages 309–336): Michel Soustelle
Chapter 10 Transformation by way of floor Nucleation and progress (pages 337–378): Michel Soustelle
Chapter eleven Modeling and Experiments (pages 379–406): Michel Soustelle
Chapter 12 Granular Coalescence (pages 407–448): Michel Soustelle
Chapter thirteen Decomposition Reactions of Solids (pages 449–488): Michel Soustelle
Chapter 14 Reactions among Solids (pages 489–542): Gerard Thomas
Chapter 15 Gas?Solid Reactions (pages 543–602): Michel Soustelle
Chapter sixteen changes of strong options (pages 603–650): Michel Soustelle
Chapter 17 Modeling of Mechanisms (pages 651–708): Michel Soustelle
Chapter 18 Mechanisms and Kinetic legislation (pages 709–778): Michel Soustelle
Chapter 19 Mechanisms and Reactivity (pages 779–844): Michel Soustelle

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Extra info for Handbook of Heterogenous Kinetics

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Because of possible confusion with the representation of vanadium, which has the same symbol, the IUPAC recommends to modify, in the case of the use of structure elements, the V symbol of vanadium and to replace it by the Va symbol. x Al3+ ion in normal position (qe = 0)…. 1. 2. Symbols of the free charges Ion Al3+ in interstitial position (qe = 3) … Al°°° i Ion O2− in interstitial position (qe = −2)….. 3. …. V′′′ Al Vacancy of O2− ion (qe = −2) ……………………………… VO°° Vacancy of Al3+ ion trapping an electron hole (qe = −2)..

X Al3+ ion in normal position (qe = 0)…. 1. 2. Symbols of the free charges Ion Al3+ in interstitial position (qe = 3) … Al°°° i Ion O2− in interstitial position (qe = −2)….. 3. …. V′′′ Al Vacancy of O2− ion (qe = −2) ……………………………… VO°° Vacancy of Al3+ ion trapping an electron hole (qe = −2).. VAl′′ Vacancy of O2− ion trapping an electron (qe = 1)…………. 4. Symbols of the lacunar structure elements Associations of structure elements are represented by indicating between brackets the associated elements without their effective charge and, after the bracket, the effective charge of the unit.

7. Textural characterizations of the solids Textural (or morphological) analysis of the solids concerns mainly the following: – Measurement of specific area, that is, the area per unit of mass. To measure this, the area required for the physical adsorption of a gas at the boiling point of liquid nitrogen is considered. The adsorbed gas is either nitrogen for surfaces more than a square meter per gram or krypton for lower surfaces. 35. – Characterization of porosity, that is, determination of the porous volume of a sample and the distribution of the diameters of pores (taken in general as cylindrical).

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